Chemistry
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Chlorine Reactions

Chlorine Reactions

Chlorine is a chemical element that can be found in group 17 of the periodic table. It's atomic number is 17. In this article, we will dive deep into the topic of Chlorine Reactions.

We will start by explaining the differences between chlorine, chloride, and chlorate(I). After that, we will take a look at the way chlorine and chlorate(I) are used to treat wastewater, along with the reaction between chlorine and sodium hydroxide. Furthermore, we will explore the reactions of chlorine with oxygen, sodium, and other halide solutions. Lastly, we will weigh the pros and cons of using chlorine in wastewater treatment. By the end of this article, you will have a better understanding of the importance of Chlorine Reactions and how they impact our daily lives. So, let's get started!

What are chlorine, chloride, and chlorate(I)?

Before we go any further, we need to look at some of the species related to chlorine: chloride and chlorate(I). Despite their similar names, they do have their differences and you shouldn’t get them mixed up.

Chlorine

As we mentioned before, chlorine is a halogen in group 17 on the periodic table. At room temperature, it is found as a yellow diatomic gas. This means that each molecule of chlorine is made up of two chlorine atoms covalently bonded together. The molecule is neutral, and each chlorine atom within the molecule has an oxidation state of +0.

A chlorine molecule
A chlorine molecule

Chloride

If you take a chlorine atom and add on an electron, you’ll end up with chloride. Chloride is a negative chlorine ion with a charge of -1 and oxidation state of -1. In fact, in most - but not all - compounds containing chlorine, you’ll find it with this oxidation state.

‍A chloride ion
A chloride ion

Chlorate(I)

When chlorine bonds to oxygen and picks up an extra electron, it forms the chlorate(I) ion, . This is a negative ion with a charge of -1. It is also known as hypochlorite.

A chlorate(I) ion
A chlorate(I) ion

Let's dive into the oxidation states within the compound. Give it a go and see if you can work them out yourself.

In an ion, the total of all the oxidation states adds up to the charge on the ion. In this case, they should add up to -1. In a compound, the element with the highest electronegativity usually has the lowest oxidation state. In this compound, oxygen is that element.

It's important to note that oxygen always has an oxidation state of -2, except in a few special cases. So, for all the oxidation states in the compound to add up to -1, chlorine must have an oxidation state of +1. This might come as a surprise, as chlorine usually has an oxidation state of -1. However, in this compound, it takes the higher oxidation state because it is less electronegative than oxygen. When people talk about chlorate, they're usually referring to chlorate(V). This is a different ion with the formula . The Roman numeral indicates the oxidation state of one of the elements in a compound. In chlorate(V), chlorine has an oxidation state of +5. If you're finding it hard to understand oxidation states, don't worry. Check out Redox for more information.

How does chlorine react with water?

Chlorine plays many roles in everyday life, but we’re going to focus specifically on one of its main uses: treating wastewater.

Reaction of chlorine with water

When chlorine reacts with water, it forms a mixture of hydrochloric acid, , and chloric acid, . Chloric acid is also known as hypochlorous acid and is based on the chlorate ion,  . It is a powerful oxidising agent that kills all sorts of bacteria and viruses, from common colds to cholera. We use this technique to disinfect water for both swimming pools and for drinking purposes. The equation is given below.

Let’s look at the oxidation states of chlorine in the three different species.

In , it has an oxidation state of +0.In , it has an oxidation state of -1.In , it has an oxidation state of +1.

This means that chlorine has been both oxidised and reduced. This reaction is therefore an example of a disproportionation reaction.

In a disproportionation reaction, some atoms of an element are oxidised and some are reduced.

Reaction of chlorine with water in sunlight

In sunlight, a different reaction occurs. The chlorine and water instead break down into oxygen and hydrochloric acid.

 

Reaction of chlorate(I) with water

Instead of adding chlorine directly, we can also treat water using chlorate(I) ions. We get these from solid sodium or calcium chlorate(I), another compound based on chlorate(I). They react with water to produce sodium ions, hydroxide ions, and chloric acid.

This is a reversible reaction - it doesn’t go to completion. To keep the equilibrium on the right, we keep the solution slightly acidic. However, the pH is always monitored closely to ensure that the water is safe for our use, be it for washing, swimming, or drinking.

How does chlorine react with alkalis?

The reaction between chlorine and an alkali such as sodium hydroxide doesn’t give us chloric acid, but instead sodium chlorate(I), which we met above. Again, this is used to treat wastewater, but it is also the active ingredient in household bleach.

Solutions containing sodium chlorate(I) are particularly useful for removing stains on cutlery caused by tannins in tea.

The equation is given below: This is another example of a disproportionation reaction. Chlorine atoms are both oxidised to make sodium chlorate(I) and reduced to make sodium chloride.

The reaction between chlorine and sodium hydroxide
The reaction between chlorine and sodium hydroxide

You might have heard of Ignaz Semmelweis, one of the founders of modern hygiene practices in hospitals and surgeries. Semmelweis noticed that a strangely high proportion of babies delivered by certain doctors were dying soon after birth, compared to those delivered by midwives. These doctors often came straight from dissecting rooms where they were working on cadavers. Semmelweis proposed that they were carrying 'cadaveric particles' that transmitted decay from dead corpse to newborn child. He found that a simple solution of chlorine dissolved in water was an effective way of stopping the spread of disease.

How else does chlorine react?

Chlorine can also react with sodium and with other solutions of halide ions.

Reaction of chlorine with sodium

Chlorine reacts with sodium to form a staple ingredient that is vital to our health and wellbeing - sodium chloride, often referred to simply as salt. This is an example of a redox reaction that forms an ionic compound. The equation is shown below.

 

Salt frequently gets a bad reputation. We’re told that it raises blood pressure and leads to heart disease and sometimes even early death. However, our cells need salt to function. Without salt, cells wouldn’t be able to regulate the movement of water in or out of themselves by osmosis. Nerve cells in particular rely on salts - they use the movement of ions to send impulses from sensory organs through to the central nervous system and out to muscles. Too much salt may be bad for us - but too little salt is definitely an issue as well.

Reaction of chlorine with halide ions

Chlorine is a halogen. Halogens take part in displacement reactions - a more reactive halogen will displace a less reactive halide ion from an aqueous solution.

Halogens get less reactive as you go down the group in the periodic table. This means that chlorine can displace bromide and iodide ions. However, it can’t displace fluoride ions.

For example, if you react chlorine with sodium bromide, chlorine will displace the bromide ions to form sodium chloride and bromine:

 

Reaction of chlorine with oxygen

Chlorine doesn’t normally react with oxygen. However, in the presence of UV light, chlorine can react with oxygen or ozone molecules to form the chlorine monoxide free radical, :

 

Like all radicals, this species is extremely reactive and can break down ozone in the ozone layer.

To find out more about how chlorine destroys ozone, check out Ozone Depletion.

Pros and cons of chlorinating water

In 1897, Maidstone, England, became the first town to have its entire water supply treated directly with chlorine. Widespread permanent chlorination started in 1905 when the city of Lincoln suffered a serious typhoid epidemic. Since then, chlorine has played a major part in preventing disease and keeping our drinking and washing water clean. However, there are both positives and negatives associated with chlorinating water.

Pros

As we’ve already mentioned, chlorinating water is first and foremost an effective way of killing off all manner of pathogens. It has helped prevent millions of deaths worldwide and this shouldn’t be underestimated.

Other advantages include:

It is cheap and economical. It is widely available. It can be used on both large and small scales.

How does chlorine kill pathogens? Both chlorine and chloric acid are uncharged molecules that are able to disrupt the cell wall in bacteria and other pathogens. Once within the cell, they oxidise proteins and enzymes, damaging them so the cell can’t function.

Cons

Although chlorinating water has its benefits, there are also some downsides to consider.

One of the drawbacks of chlorine is that it can dry out the skin and hair. Additionally, some people find that chlorinated water has an unpleasant taste. To address this, ozone can be used as an alternative method for sterilizing water.

Another issue with chlorine is that it can react with organic compounds in water, producing disinfectant byproducts or DBPs. These byproducts have been linked to health problems such as liver and kidney cancer, heart disease, and slowed brain activity. However, it's important to note that these negative effects are rare and chlorine levels in water are closely monitored to ensure they are within safe limits. To recap, chlorine is a halogen found in group 17 of the periodic table and is commonly used to disinfect water. Chlorine reacts with water to form chloric acid and hydrochloric acid, and with sodium to form sodium chloride. Chlorinating water is an effective way to kill harmful pathogens, but it's important to be aware of the potential negative effects of chlorine on human health.

Chlorine Reactions

What happens when chlorine reacts with potassium bromide solution?

Chlorine reacts with potassium bromide to form potassium chloride and bromine. This is an example of a displacement reaction.

Which elements react violently with chlorine? 

Group 1 elements react violently with chlorine.

What is the reaction of chlorine with water? 

Chlorine reacts with water to form a mixture of hydrochloric acid and chloric acid. In sunlight, a different reaction occurs - chlorine and water react to form oxygen and hydrochloric acid.

Is reacting a hydrocarbon with chlorine an endothermic reaction?

The free radical substitution of a hydrocarbon by chlorine is exothermic, not endothermic.

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